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Ethanol
What is Ethanol
Ethanol (ethyl alcohol, grain alcohol, ETOH) is a clear, colorless
liquid with a characteristic, agreeable odor. In dilute aqueous
solution, it has a somewhat sweet flavor, but in more concentrated
solutions it has a burning taste. Ethanol, CH3CH2OH, is an
alcohol, a group of chemical compounds whose molecules contain
a hydroxyl group, -OH, bonded to a carbon atom. The word alcohol
derives from Arabic al-kuhul, which denotes a fine powder
of antimony produced by distilling antimony and used as an
eye makeup. Alcohol originally referred to any fine powder,
but medieval alchemists later applied the term to the refined
products of distillation, and this led to the current usage.
Ethanol melts at -114.1°C, boils at 78.5°C, and
has a density of 0.789 g/mL at 20°C. Its low freezing
point has made it useful as the fluid in thermometers for
temperatures below -40°C, the freezing point of mercury,
and for other low-temperature purposes, such as for antifreeze
in automobile radiators.
Ethanol has been made since ancient times by the fermentation
of sugars. All beverage ethanol and more than half of industrial
ethanol is still made by this process. Simple sugars are
the raw material. Zymase, an enzyme from yeast, changes
the simple sugars into ethanol and carbon dioxide. The fermentation
reaction, represented by the simple equation C6H12O6 2 CH3CH2OH
+ 2 CO2 is actually very complex, and impure cultures of
yeast produce varying amounts of other substances, including
glycerine and various organic acids. In the production of
beverages, such as whiskey and brandy, the impurities supply
the flavor. Starches from potatoes, corn, wheat, and other
plants can also be used in the production of ethanol by
fermentation. However, the starches must first be broken
down into simple sugars. An enzyme released by germinating
barley, diastase, converts starches into sugars. Thus, the
germination of barley, called malting, is the first step
in brewing beer from starchy plants, such as corn and wheat.
Ethanol as a Fuel
Ethanol is used as an automotive fuel by itself and can be
mixed with gasoline to form what has been called "gasohol"
FUEL ETHANOL- the most common blends contain 10% ethanol and
85% ethanol mixed with gasoline. Over 1 billion gallons of
ethanol are blended with gasoline every year in the United
States. Because the ethanol molecule contains oxygen, it allows
the engine to more completely combust the fuel, resulting
in fewer emissions. Since ethanol is produced from plants
that harness the power of the sun, ethanol is also considered
a renewable fuel. Therefore, ethanol has many advantages as
an automotive fuel.
Most industrial ethanol is denatured to prevent its use
as a beverage. Denatured ethanol contains small amounts,
1 or 2 percent each, of several different unpleasant or
poisonous substances. The removal of all these substances
would involve a series of treatments more expensive than
the federal excise tax on alcoholic beverages (currently
about $20 per gallon). These denaturants render ethanol
unfit for some industrial uses. In such industries undenatured
ethanol is used under close federal supervision.